CHEMISTRY 112                                                       WILLIAM VINING

SECTIONS 4-6                                                           232 PHYSICAL SCIENCES BLDG.

Spring 2008                                                                 ViningWJ@oneonta.edu

Office Hours: M 3-4, T 12-1, F 11-12                         Phone 436-2698

                                               

Links to Materials

Simulations

Laboratory Technique Videos

 

 

OWL Login Page

 

 

  Textbook Chapter Downloads

General Chemistry I Chapters for Reference

Text Chapter 1

Text Chapter 2

Text Chapter 3

Text Chapter 4

     Chapter 4 Organic Reactions Supplement

Text Chapter 5 Replacement

Text Chapter 6

Text Chapter 7

 

Text Chapters for this Course:

Text Chapter 8: Bonding and Molecular Structure

Text Chapter 9: Advanced Chemical Bonding

Text Chapter 10: Gases

Kinetics

Thermodynamics

            Equilibrium

            Acid-Base Chemistry I

            Acid-Base Chemistry II

            Precipitation and Complexation Chemistry

 

   Exam Things

            Practice Exam #1-2008

            Practice Exam #1-2008 Answer Key

            Exam #1 Answer Key

                                    Page 1, Page 2, Page 3, Page 4, Page 5, Page 6

 

            Exam #2 Topics

            Practice Exam #2

            Practice Exam #2 Answers

            Exam, #2 Answer Key

                                    Page 1, Page 2, Page 3, Page 4, Page 5

 

 

Practice Exam #3

Practice Exam #3 Answers

            Exam, #2 Answer Key

                                    Page 1, Page 2, Page 3, Page 4

 

            Sample Electrochemistry Questions

 

   Lecture PowerPoint Files

            Chapter 8: Molecular Structure

            Chapter 9 Part 1: Valence Bond Theory

Chapter 12: Solutions

            Chapter 13: Kinetics

Chapter 19 Entropy

 

Annotated PowerPoint Files

Chapter 9: Valence Bond Theory

Chapter 9: Molecular Orbital Theory

Chapter 13: Kinetics Part 1

Chapter 13: Kinetics Part 2

Chapter 19: Thermodynamics

Chapter 11: Liquids, Solids, IMFs

Chapter 12: Solutions

Chapter 12: Colligative Properties

Chapter 15: Introduction to Equilibria

Chapter 16: Acid-Base Equilibria

Chapter 17: Buffers

Chapter 18: Solubility and Complexation Equilibria

Chapter 20: Electrochemistry

 

 

Other Downloads

         Periodic Table

         Review: Orbitals and Electron Configurations

         Review: Periodic Properties of the Elements

 

         Course Overview

 

         Chapter 8 Review

         Covalent and Ionic Bonding

         Valence Electrons and Lewis Structures

         How to Draw Lewis Structures

         Trends in Properties of Bonds

         Resonance, Oxidation Numbers and Formal Charge

         Lewis Structure Examples

 

         Chapter 8 New Material

         Valence Electrons and Molecular Structure

         Molecular Structures

         How to Determine Molecular Structure

         Table of Molecular Structures

         Model Building Worksheet (for Plastic Models)

Molecular Structure and Polarity

 

         Chapter 9

         Valence Bond Theory: Handout 1

Hybrid Orbitals Handout

Hybrid Orbitals and Pi Bonding

Hybrid Orbitals: Expanded Valence

Molecular Orbitals Handout

Another Molecular Orbitals Handout

Band Theory Handout

 

Chapter 10

Gas Laws Handout

Gas Law Examples

Kinetic Molecular Theory Handout

 

Chapter 11 IMFs, Liquids and Solids

Band Theory and Metallic Bonding

IMFs

Compounds and IMFs

Hydrogen Bonding

Solids

Unit Cell Types

Unit Cells and Compound Formulas

 

Chapter 12 Solutions

Factors Affecting Solubility

Water and Oil

Soap Movie

Protein Folding

Laundry

 

Chapter 14 Kinetics

Rate Laws and Concentration-Time Equations

Determining Rate Laws: Initial Rates

Graphical Method for Finding a Rate Law

Concentration-Time Relationships

Half-Life

Arrhenius Equation

Reaction Coordinate Diagrams

Reaction Mechanism Examples

More Reaction Mechanism Examples

Bleaching of Green Food Dye

 

Chapter 15 Equilibrium
Equilibrium Handout 1: Microscopic Reversibility

Equilibrium Handout 2: Equilibrium Constant Expressions

Equilibrium Handout 3: Concentration-Time Curves and K

LeChatelier’s Principle

 

Chapter 16 Acid-Base Chemistry I

Acid-Base Equilibria

Acid-Base Examples

Acid-Base Table/Acid Strength and Molecular Structure

Lewis Acids and Bases

 

Chapter 17 Acid-Base Chemistry II

Titration Curves and Alpha Plots

Acid-Base States of Glycine

Buffer Solutions

Buffer pH

 

Chapter 18 Solubility and Complexation Equilibria

Solubility and Complexation Equilibira Examples

 

Chapter 19 Entropy and Free Energy

Entropy Handout

Thermo Data Tables for Class

 

 

Spectroscopy Materials

IR/NMR Website        

         IR Table and Spectra

Mass Spectra Examples

NMR Table and Spectra

 

 

LABORATORY SCHEDULE

 

Week              Laboratory Experiment (click on experiment to download handout)

1/21                 Determination of the Molar Mass of a Volatile Liquid

1/28                 Gas Chromatography

2/4                   Silver Group Analysis

2/11                 Anion Analysis

2/18                 Vacation

2/25                 Kinetics (1)

3/3                   Kinetics (2)

3/10                 Analysis of Bond Strengths

3/17                 Separations (1)

3/24                 Vacation

3/31                 Complex Ions

4/7                   Acid-Base Chemistry: Prelab, Experiment, Data Sheets

4/14                 Dynamic Equilibrium

4/21                 Forensic Acid-Base Analysis

4/28                 Check Out

 

 

 

 

SYLLABUS

                       

PREREQUISITE

The prerequisite for General Chemistry II is General Chemistry I, Chem 111.

 

MATERIALS

  • General Chemistry to Accompany the OWL Electronic Learning System: Provided
  • Laboratory Experiments (download from course website)
  • Laboratory Safety Goggles (bookstore)
  • Scientific Calculator
  • OWL Electronic Homework System (provided by instructor)

 

GRADING

The basis for course grades is determined by examinations, graded homework, and laboratory. Points for each are:

 

Three hour exams (100 points each):                 300 points

Comprehensive final exam:                                150 points

Homework                                                       100 points

Laboratory:                                                      100 points

Total Points:                                                     650 points

 

Letter grade ranges on a percentage basis are:

 

A         90.0 – 100%                C-        67.0 – 69.9%

A-        87.0 – 89.9%               D+       64.0 – 66.9%

B+       84.0 – 86.9%               D         60.0 – 63.9%

B         80.0 – 83.9%               D-        57.0 – 59.9%

B-        77.0 – 79.9%               E          Below 57%

C+       74.0 – 76.9%

C         70.0 – 73.9%

 

EXAMINATIONS

 

Exams will be held on the following Thursday evenings from 7-9 PM in IRC 3.

 

            Feb. 14, Mar 20, April 30     

 

If you miss an examination because of circumstances beyond your control, please inform the instructor immediately. A make-up examination will be scheduled for as soon as possible. The instructor must be notified before or during the examination time.


OWL HOMEWORK

Homework will use the OWL system served by the University of Massachusetts. The system is “mastery” based, meaning that you can work on an assignment as long as you want and try questions as many times as you want, until succeeding. There is no penalty for getting an answer wrong. There is only a penalty for not eventually getting it right.

 

The login address is: http://owl.oit.umass.edu

 

Choose General Chemistry/UMass Amherst

 

Your login is SUCO + your last name. So, mine is SUCOvining.

Your password is your student number.

 

Assignments will be made weekly and will be due at midnight on Sunday.

 

 

LABORATORY

The laboratory work is an integral and essential part of this course and will represent a significant factor in your final grade (see above). Normally, you will not be granted credit for this course unless you satisfactorily complete the laboratory work; however, if you have taken the course previously at SUCO and completed the laboratory work, a waiver may be granted. If you think that you might qualify for such a waiver, discuss your situation with the lecture instructor as soon as possible.

You will be expected to attend every scheduled meeting of your laboratory section. If you are forced to miss one of the labs due to circumstances beyond your control, the instructor will attempt to arrange for you to attend some other laboratory section during the same week. If it is impossible to reschedule the experiment you should discuss methods of making up the work with your instructor.

Students will not be permitted to work in any laboratory section other than that for which they are scheduled. Students must not work in the laboratory with direct faculty supervision.

 
Unless you are informed otherwise, laboratory reports will be due the first lecture meeting after the completion of the experiment.


In order to protect your vision you will be required to wear safety glasses while you are in the laboratory. If you violate this rule you become a hazard to yourself as well as those around you. Therefore, you may be asked to leave the laboratory if you do not wear safety glasses.

Laboratory reports are to represent your own original work. You will sometimes work with other students to collect data, but your written report, including calculations must be your own work.

 


Chemistry 112-Spring 2008/Vining

 

 

COURSE SCHEDULE

Week               Chapter            Subject

1/16                 8                      Molecular Structure

1/21                 9                      Bonding Theories

1/28                 9                      Bonding Theories

2/4                   13                    Kinetics

2/11                 13                    Kinetics

2/18                 Vacation

2/25                 18                    Entropy and Free Energy

3/3                   10                    Liquids and Solids

3/10                 11                    Liquids and Solids

3/17                 11                    Solutions

3/24                 Vacation

3/31                 12                    Equilibrium

4/7                   14                    Acids and Bases

4/14                 15                    Advanced Acid-Base Equilibria

4/21                 16                    Oxidation-Reduction and Electrochemistry